Pillararene-based host-guest interactions
Pillararene-based host-guest interactions were employed to construct a series of supramolecular amphiphiles not only in organic solvent but also in water.3 For example, we constructed a novel supramolecular amphiphile based on a pillar6arene and an azobenzene-containing guest in an organic solvent, which underwent a photoresponsive threading-dethreading switch upon UV and visible light irradiation due to the trans−cis photoisomerization of the guest, accompanied by disassembly and assembly of the corresponding aggregates.3a
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